2 · In some cases boiler feedwater is suitable; however, frequently additional purification is required. In all cases the spray water should be obtained from a source that is free of deposit forming and corrosive chemicals such as sodium hydroxide, sodium sulfite, sodium phosphate, iron, and copper.
2015-2-22 · The sodium-to-phosphate ratio in this precipitate is usually lower than that in the bulk water. Thus, as the boiler comes up in load, sodium phosphate begins to precipitate, leaving the remaining chemical in solution with a sodium phosphate ratio greater than 3:1.
2 · It has been known for quite some time that these blended phosphates can precipitate at much lower sodium-to-phosphate ratios than even 2.3:1, which can then cause direct acid phosphate corrosion
2020-8-3 · pH table for Potassium and Sodium Phosphate Buffers. pH table for Potassium phosphate buffer at 25°C; pH % K 2 HPO 4 (dibasic) % KH 2 PO 4 (monobasic); 5.8: 8.5: 91
2 · Rather, it establishes phosphate and pH target ranges that are generally consistent with maintaining the correct sodium to phosphate ratios in the boiler bulk water. The pH / phosphate data must still be plotted by supervisors and verified to be in compliance with the PC limits.
BOILER AID 610 is a special blend of phosphates, chelates, sodium hydroxide, as well as organic dispersing agents designed specifically for the treatment of low and high pressure boilers where there is a desire to use only one treatment. BOILER AID 610Amine: Steam boiler all in one treatment with amine.
2007-2-19 · pressure boiler using a phosphate treatment program. It should be recognized that striving to get a specific Na to PO4 ratio can actually be harmful to the operation of a boiler. The control of a phosphate program must put a major effort to ensuring that the pH vs. Concentration of Phosphate for Varying Sodium-Phosphate Ratios ppm 0.10.30.5
2014-5-15 · When tri-sodium phosphate is used, 98% of the salt will hydrolyse to di-sodium phosphate and sodium hydroxide according to the following reaction. 3 4 2 + → 2 4 + Na PO H O Na HPO NaOH (8) Thus one mole tri-sodium phosphate will increase boiler water pH equivalent to one mole sodium hydroxide if boiler water pH is in the range of 9 to 10.0
2015-5-15 · Congruent phosphate control is the boiler water internal treatment most widely used in many industries, such as pulp and paper, chemical, petrochemical and in many applications for the power generation. The great benefit lays on the ability of this program to absorb small
2018-8-22 · case, but normally only tri and di-sodium phosphate will be required to counter normal contaminant variation in the incoming boiler feedwater. Most water treatment companies can provide blends of sodium phosphate products at various sodium to phosphate molar ratios. Figure 1: Relative corrosion of carbon steel by HCI and NaOH at 590°F (310°C).
2018-6-13 · Because each boiler is on congruent phosphate control, sodium-to-phosphate ratios must he monitored closely. In 1986 and 1992, Power Engineering pub- lished articles outlining a method to calculate NaiPO, ratios. Plant engineers wrote these calculations into the ladder logic of the PLC, and the values are con- tinuously trended on remote data
Boiler Water Treatment Chemicals. As well as being a service company Feedwater also manufactures and supplies a range of high-quality boiler water treatment chemicals for UK and export customers. Our chemicals are suitable for land, marine and heritage steam boilers.. A badly treated steam boiler is a potential bomb, so getting the feed water quality and boiler water chemistry correct is
2020-12-21 · Sodium erythorbate and neutralising amine based formulation. Polymer and phosphate based formulation. A boiler feedwater treatment for the control of scale. Suitable for low hardness, softened and de-alkalised feedwater. More concentrated formulation of BV219 but with differing amine ratios. BV452: Combination of 3 neutralising amines.
A pH/phosphate program in a boiler water system is controlled by: (1) determining the feed rate of the phosphate to the boiler by adding to a phosphate-feed stream containing the phosphate feeding to the boiler a phosphate-feed tracer in known proportion to the phosphate, determining the concentration of the phosphate-feed tracer in the phosphate-feed stream and correlating the phosphate-feed
2020-12-28 · Sodium nitrate is the standard treatment for inhibiting embrittlement in boilers operating at low pressures. The ratios of sodium nitrate to sodium hydroxide in the boiler water recommended by the Bureau of Mines depend on the boiler operating pressure. These ratios are as follows:
In investigating phosphate hideout, sodium to phosphate molar ratios were determined of 3.8 for the HP boiler water and 3.0 for the IP boiler water. As the molar ratio of sodium to phosphate should be 3.0 with tri-sodium phosphate, this showed the presence of free sodium hydroxide in the HP boiler water. 294 PowerPlant Chemistry 2012, 14(5) PPC hem
The upper boundaries of the boxes are the various ratios of sodium to phosphate, from 3.0:1 to 2.6:1, depending on pressure, where trisodium phosphate (TSP) species compose 100 percent of the
Boiler Water Treatment Chemical Guidelines—Part Il continued Because of the associated corrosion problems, chelants are not the preferred treatment choice. However, if the system dictates the use of chelating agents, it can feed under "starvation" conditions, i.e., no free residual in the boiler. Based on the trace level of hardness in the boiler
2 · This is referred to as phosphate corrosion. This produces unique wastage morphologies and characteristic corrosion products of NaFePO[sub 4]. Caustic corrosion produces well-defined depressions or gouges, as does phosphate attack at lower sodium-to-phosphate ratios. An example is a 1,300 psi (9 MPa) and 930 F (500 C) boiler.
Using Of Congruent Phosphate As Equilibrium Phosphate Boilers Water Treatment